Ammonia → Sorbitan mono-(9Z)-9-octadecenoate

HRID 653553

반응식

HRID 653553 반응식
[C:1]([OH:5])(=[O:4])[CH:2]=[CH2:3].[C:6](N)(=[O:9])[CH:7]=[CH2:8].[CH2:11]1[O:13][CH2:12]1.C(O[C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][C:20]=1[CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH3:33])(=O)C=C.N.C(N(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O)CN(CC([O-])=O)C[C:39]([O-])=[O:40].[Na+].[Na+].[Na+].[Na+].[Na+].C(C=CC(N)=O)C=CC(N)=[O:71]>O>[CH3:33][CH2:32][CH2:31][CH2:30][CH2:29][CH2:28][CH2:27][CH2:26]/[CH:25]=[CH:20]\[CH2:19][CH2:24][CH2:23][CH2:22][CH2:21][CH2:3][CH2:2][C:1]([O:5][CH2:8][C@@H:7]([OH:71])[C@H:6]1[O:9][CH2:12][C@H:11]([OH:13])[C@H:39]1[OH:40])=[O:4]

참가 물질

9

반응물 7

HCID 222AmmoniaHCID 6354Ethylene OxideHCID 6579AcrylamideHCID 6581Acrylic AcidHCID 8779Pentasodium PentetateHCID 21884854HCID 21884854, 화합물HCID 53800990Methylene-bisacrylamide

생성물 1

HCID 9920342Sorbitan mono-(9Z)-9-octadecenoate

시약·촉매·용매 1

HCID 962Water용매2회

실험 절차

115.2 parts of acrylic acid, 28.8 parts of acrylamide, 2.3 parts of a 9 mole ethylene oxide condensate of nonylphenol acrylate (a water soluble derivative), 220 parts of water, 65 parts 32% aqueous ammonia, 0.4 parts of Tetralon B (trade mark), 0.04 parts of AZDN and 0.04 parts of methylene bis-acrylamide were mixed to form an aqueous phase. A non-aqueous liquid phase was formed of 15 parts Span 80, 42 parts of a 30% w/w solution of a 1:2 molar copolymer of cetostearyl methacrylate:methacrylic acid in SBP11, 117 parts of Pale Oil 150 and 149 parts of SBP11. The aqueous phase was homogenised into the oil phase, deoxygenated and polymerised using 0.043 parts of sodium metabisulphite and 0.043 parts of tertiary butyl hydroperoxide. The resulting inverse dispersion of hydrated polymer gel was dehydrated by distillation under reduced pressure to a final pressure of 10 mm of mercury at a temperature of 95° C.

후처리

  1. customto form an aqueous phase

출처 및 근거

ORD 기록
ord-f1afee50d34f4971b08e41181bf73df6
출처 데이터셋
uspto-grants-1987_06
특허 번호
US04677152

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