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Methacrylic Acid → Ethyl acrylate methyl methacrylate

HRID 654875
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HRID 654875 반응식
[C:1]([O:5][CH2:6][CH3:7])(=[O:4])[CH:2]=[CH2:3].[C:8]([O:13][CH3:14])(=[O:12])[C:9]([CH3:11])=[CH2:10].C(O)(=O)C(C)=C.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1.O.N>O.C(O)(C)C>[C:1]([O:5][CH2:6][CH3:7])(=[O:4])[CH:2]=[CH2:3].[C:8]([O:13][CH3:14])(=[O:12])[C:9]([CH3:11])=[CH2:10]
참가 물질실험 절차후처리출처 및 근거반응 노트

참가 물질

8

반응물 5

HCID 4093Methacrylic AcidHCID 6658Methyl MethacrylateHCID 7187Benzoyl PeroxideHCID 8821Ethyl AcrylateHCID 12896473Azane;hydrate

생성물 1

HCID 62704Ethyl acrylate methyl methacrylate

시약·촉매·용매 2

HCID 962
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Water
용매
HCID 3776Isopropanol용매

실험 절차

To 150 g of isopropanol were added 55 g of ethyl acrylate, 35 g of methyl methacrylate and 10 g of methacrylic acid. To the resulting mixture was added 0.5 g of benzoyl peroxide, and thereafter, the mixture thus-obtained was subjected to polymerization reaction at 80° C. for 7 hours. Subsequently, 200 g of water and 4 g of 28% ammonia water were added thereto, and then, the isopropanol was completely removed by distillation to obtain an ethyl acrylate/methyl methacrylate copolymer.

후처리

  1. customthe mixture thus-obtained
  2. customwas subjected to polymerization reaction at 80° C. for 7 hours
  3. customthe isopropanol was completely removed by distillation

출처 및 근거

ORD 기록
ord-1334f21ecacd496b96c85f1ba489d456
출처 데이터셋
uspto-grants-1992_07
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US05134189

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