3-Chloro-2-methyl-1-propene → Chloro(3-chloro-2-methylpropyl)dimethylsilane

HRID 65495

반응식

HRID 65495 반응식
[SiH:1]([Cl:4])([CH3:3])[CH3:2].[CH2:5]([Cl:9])[C:6](=[CH2:8])[CH3:7]>>[Si:1]([CH2:7][CH:6]([CH2:5][Cl:9])[CH3:8])([CH3:3])([CH3:2])[Cl:4]

참가 물질

3

반응물 2

HCID 112413-Chloro-2-methyl-1-propeneHCID 66108Chlorodimethylsilane

생성물 1

HCID 86665Chloro(3-chloro-2-methylpropyl)dimethylsilane수율 717.2%

실험 절차

In a 100 ml apparatus, there were combined 22.3 g (0.1 mol) of MD'M, 9.5 g (0.01 mol) of Me2SiHCl, and 9.1 g (0.1 mol) of methallyl chloride, followed by 0.015 ml Pt catalyst solution at 50° C. There was an exothermic reaction to 96° C. in 6 min. The complete reaction was vacuum distilled yielding 13.28 g (71.8%) of Me2SiClCH2CHMeCH2Cl and 8.63 g (27.6%) of M2D'CH2CHMeCH2Cl. This example indicates that neither MD'M nor Me2SiHCl is an effective promoter for reaction of the other with methallyl chloride when used at the equimolar level. The yield based on methallyl chloride was 99.4%, indicating very efficient reaction of the olefinic reactant.

후처리

  1. customan exothermic reaction to 96° C. in 6 min
  2. customThe complete reaction
  3. distillationdistilled

출처 및 근거

ORD 기록
ord-d15f2fc3708a449485f4047fa7ff44e8
출처 데이터셋
uspto-grants-1986_09
특허 번호
US04614812

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