Methyldichlorosilane → Silane, dichloro(3-chloro-2-methylpropyl)methyl-

HRID 65500

반응식

HRID 65500 반응식
[SiH:1]([Cl:4])([Cl:3])[Cl:2].[CH2:5]([Cl:9])[C:6](=[CH2:8])[CH3:7].[CH3:10][SiH:11]([Cl:13])[Cl:12]>>[CH3:10][Si:11]([CH2:8][CH:6]([CH2:5][Cl:9])[CH3:7])([Cl:13])[Cl:12].[Si:1]([CH2:7][CH:6]([CH2:5][Cl:9])[CH3:8])([Cl:4])([Cl:3])[Cl:2]

참가 물질

5

반응물 3

HCID 6376MethyldichlorosilaneHCID 112413-Chloro-2-methyl-1-propeneHCID 24811Trichlorosilane

생성물 2

HCID 86664Silane, trichloro(3-chloro-2-methylpropyl)-수율 21.5%HCID 102659Silane, dichloro(3-chloro-2-methylpropyl)methyl-수율 68.8%

실험 절차

In a 100 ml apparatus, there as combined 13.6 g (0.1 mol) of Cl3SiH, 9.1 g (0.1 mol) of methallyl chloride, and 11.5 g (0.1 mol) of MeSiHCl2, followed by 0.05 ml Pt catalyst solution at 21° C. Gentle heating caused an exothermic reaction to 52° C. in 22 min. The complete reaction was vacuum distilled, yielding 14.14 g (68.8%) of MeSiCl2CH2CHMeCH2Cl and 4.86 g (21.5%) of Cl3SiCH2CHMeCH2Cl. This example indicates that at the equimolar level, neither Cl3SiH nor MeSiHCl2 is an effective promoter for reactions of the other with methallyl chloride.

후처리

  1. temperatureGentle heating
  2. customan exothermic reaction to 52° C. in 22 min
  3. customThe complete reaction
  4. distillationdistilled

출처 및 근거

ORD 기록
ord-c12899d85d1249d1b179e11e3daa130e
출처 데이터셋
uspto-grants-1986_09
특허 번호
US04614812

연결된 노트

불러오는 중…