3-Chloro-2-methyl-1-propene → Chloro(3-chloro-2-methylpropyl)dimethylsilane

HRID 65501

반응식

HRID 65501 반응식
[SiH:1]([Cl:4])([CH3:3])[CH3:2].[CH2:5]([Cl:9])[C:6](=[CH2:8])[CH3:7]>>[Si:1]([CH2:7][CH:6]([CH2:5][Cl:9])[CH3:8])([CH3:3])([CH3:2])[Cl:4]

참가 물질

3

반응물 2

HCID 112413-Chloro-2-methyl-1-propeneHCID 66108Chlorodimethylsilane

생성물 1

HCID 86665Chloro(3-chloro-2-methylpropyl)dimethylsilane수율 83.4%

반응 조건

온도
80 °C

실험 절차

In a 100 ml apparatus, there were combined 14.2 g (0.15 mol) of Me2SiHCl and 13.6 g (0.15 mol) of methallyl chloride, followed by 0.05 ml Pt catalyst solution at 21° C. Gentle heating caused a smooth exothermic reaction to 90° C. in 16 in. Reaction was heated at 80° C. until completed (50 min). Vacuum distillation yielded 23.14 g (83.4%) of Me2SiClCH2CHMeCH2Cl.

후처리

  1. temperatureGentle heating
  2. customa smooth exothermic reaction to 90° C. in 16 in
  3. customReaction
  4. custom(50 min)
  5. distillationVacuum distillation

출처 및 근거

ORD 기록
ord-358f42d57f2345dc8b028c1b7c81a5ce
출처 데이터셋
uspto-grants-1986_09
특허 번호
US04614812

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