Pyridine → Butyl 7-(tert-butylperoxy)-3,7-dimethyloctyl carbonate

HRID 65978

반응식

HRID 65978 반응식
[CH3:1][CH:2]([CH2:6][CH2:7][CH2:8][C:9]([CH3:17])([O:11][O:12][C:13]([CH3:16])([CH3:15])[CH3:14])[CH3:10])[CH2:3][CH2:4][OH:5].N1C=CC=CC=1.Cl[C:25]([O:27][CH2:28][CH2:29][CH2:30][CH3:31])=[O:26]>C(OCC)C>[C:25](=[O:26])([O:27][CH2:28][CH2:29][CH2:30][CH3:31])[O:5][CH2:4][CH2:3][CH:2]([CH3:1])[CH2:6][CH2:7][CH2:8][C:9]([CH3:17])([O:11][O:12][C:13]([CH3:16])([CH3:15])[CH3:14])[CH3:10]

참가 물질

5

반응물 3

HCID 1049PyridineHCID 61140Butyl chloroformateHCID 536641833,7-Dimethyl-7-(t-butylperoxy)octyl alcohol

생성물 1

HCID 23346617Butyl 7-(tert-butylperoxy)-3,7-dimethyloctyl carbonate

시약·촉매·용매 1

HCID 3283Diethyl Ether용매2회

실험 절차

To a solution of 7.9 g (0.03 mole) of 3,7-dimethyl-7(t-butylperoxy)octyl alcohol and 2.4 g (0.03 mole) of pyridine in diethyl ether cooled at 10°±1° C was added a solution of 4.09 (0.03 mole) of n-butyl chloroformate in diethyl ether. The reaction temperature was maintained at 15°±1° C during the addition.

후처리

  1. temperatureThe reaction temperature was maintained at 15°±1° C during the addition

출처 및 근거

ORD 기록
ord-22cf3ce5ef674b899ba6e662b054e132
출처 데이터셋
uspto-grants-1978_12
특허 번호
US04129700

연결된 노트

불러오는 중…