4-Oxobutanoic acid → 1-Piperidinium

HRID 66157

반응식

HRID 66157 반응식
[O:1]=[CH:2][CH2:3][CH2:4][C:5]([OH:7])=[O:6].[NH:8]1[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9]1>C1C=CC=CC=1>[NH2+:8]1[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9]1.[O:1]=[CH:2][CH2:3][CH2:4][C:5]([O-:7])=[O:6]

참가 물질

5

반응물 2

HCID 11124-Oxobutanoic acidHCID 8082Piperidine

생성물 2

HCID 6379691-PiperidiniumHCID 95432384-Oxobutanoate

시약·촉매·용매 1

HCID 241Benzene용매

실험 절차

100 Mg. of 4-(8-methoxy-6,11-dihydrodibenzo-[b.e.]-thiepin-11-one-3-yl)-4-oxobutyric acid in 10 ml. of benzene is treated with 60 mg. of piperidine. The solution obtained is allowed to stand for one hour and the crystalline material which forms is filtered, washed with ether and air dried to yield piperidinium 4-(8-methoxy-6,11-dihydrodibenzo-[b.e.]-thiepin-11-one-3-yl)-4-oxobutyrate.

후처리

  1. customThe solution obtained
  2. filtrationthe crystalline material which forms is filtered
  3. washwashed with ether and air
  4. customdried

출처 및 근거

ORD 기록
ord-95cdf6991778486985518cab3455bb88
출처 데이터셋
uspto-grants-1978_12
특허 번호
US04130654

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