1,1-Dichlorosilacyclobutane → 1,1-Diacetamidosilacyclobutane

HRID 704072

반응식

HRID 704072 반응식
C[Si]([CH2:5][C:6]([NH2:8])=[O:7])(C)C.Cl[Si:10]1(Cl)[CH2:13][CH2:12][CH2:11]1>C(Cl)Cl>[C:6]([NH:8][Si:10]1([NH:8][C:6](=[O:7])[CH3:5])[CH2:13][CH2:12][CH2:11]1)(=[O:7])[CH3:5]

참가 물질

4

반응물 2

HCID 753731,1-DichlorosilacyclobutaneHCID 357676Acetamide, 2-(trimethylsilyl)-

생성물 1

HCID 200755231,1-Diacetamidosilacyclobutane

시약·촉매·용매 1

HCID 6344Dichloromethane용매

실험 절차

When 1.72 g of trimethylsilylacetamide was mixed with 0.92 g of 1,1-dichlorosilacyclobutane in 5 g of methylene chloride, a white precipitate formed. The precipitate dissoved upon shaking and slowly recrystallized as white needles. There was no trimethylchlorosilane detected in the residual fluid, indicating that the expected reaction to form 1,1-diacetamidosilacyclobutane did not occur.

후처리

  1. customa white precipitate formed
  2. customslowly recrystallized as white needles
  3. customreaction

출처 및 근거

ORD 기록
ord-c2cd10faa21e40fbbb19209d3ea4c1b8
출처 데이터셋
uspto-grants-1991_01
특허 번호
US04985565

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