Trimethoxysilane → (3-((2-Methoxyethoxy)methoxy)-2-methylpropyl)trimethoxysilane

HRID 719036

반응식

HRID 719036 반응식
[CH3:1][C:2]([CH2:4][O:5][CH2:6][O:7][CH2:8][CH2:9][O:10][CH3:11])=[CH2:3].[CH3:12][O:13][SiH:14]([O:17][CH3:18])[O:15][CH3:16]>O.Cl.Cl.Cl[Pt](Cl)(Cl)Cl.O1CCCC1>[CH3:11][O:10][CH2:9][CH2:8][O:7][CH2:6][O:5][CH2:4][CH:2]([CH3:1])[CH2:3][Si:14]([O:17][CH3:18])([O:15][CH3:16])[O:13][CH3:12]

참가 물질

5

반응물 2

HCID 17215TrimethoxysilaneHCID 43829002-Methyl-4,6,9-trioxa-1-decene

생성물 1

HCID 86690069(3-((2-Methoxyethoxy)methoxy)-2-methylpropyl)trimethoxysilane수율 60%

시약·촉매·용매 2

HCID 16211507Platinate(2-), hexachloro-, hydrogen, hydrate (1:2:1), (OC-6-11)-촉매HCID 8028Tetrahydrofuran용매

실험 절차

Into a 200-ml flask, 8.01 g (50% by mol) of 2-methyl-4,9,6-trioxa-1-decene, 0.026 g (0.05% by mol) of hexachloroplatinic(IV) acid hydrate, and 100 g of tetrahydrofuran were charged. Into the mixed solution, 7.94 g (65% by mol) of trimethoxysilane was added dropwise under a nitrogen stream with stirring with a magnetic stirrer. After the addition, the mixture was reacted at ambient temperature for 24 hours. Then, the reaction mixture was distilled to afford 8.47 g of (3-((2-methoxyethoxy)methoxy)-2-methylpropyl)trimethoxysilane (corresponding to the compound of Formula (A-29)).

후처리

  1. additionAfter the addition
  2. customthe mixture was reacted at ambient temperature for 24 hours
  3. distillationThen, the reaction mixture was distilled

출처 및 근거

ORD 기록
ord-5a73cde3f8a94288980f98938799ef44
출처 데이터셋
uspto-grants-2015_11
특허 번호
US09196484B2

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