1-Butanol → Zirconium butoxide

HRID 727988노트

반응식

HRID 727988 반응식
[CH2:1]([OH:5])[CH2:2][CH2:3][CH3:4].[Zr:6].O>C(O)CC.CC(O)C>[CH3:4][CH2:3][CH2:2][CH2:1][O-:5].[CH3:4][CH2:3][CH2:2][CH2:1][O-:5].[CH3:4][CH2:3][CH2:2][CH2:1][O-:5].[CH3:4][CH2:3][CH2:2][CH2:1][O-:5].[Zr+4:6]

참가 물질

6

반응물 3

HCID 2631-ButanolHCID 962WaterHCID 23995Zirconium

생성물 1

HCID 160560Zirconium butoxide

시약·촉매·용매 2

HCID 10311-Propanol용매2회HCID 3776Isopropanol용매

실험 절차

1 butanol (171.6 gm) was mixed with 125 ml of n-propanol and placed in a one liter, three-neck round-bottom flask under nitrogen atmosphere. The concentration of zirconium was 0.95 molar. A solution of 28.8 ml of deionized water in 125 ml of n-propanol was added through an addition funnel under nitrogen atmosphere to the solution in the flask with rapid stirring for two minutes. The stirring was stopped, and the mixture was left to stand for three hours. The mixture was then centrifuged, and the mother liquor was discarded. The solid residue was ultrasonically dispersed in 2-propanol and then centrifuged to harvest the supernatant sol. This procedure was repeated several times.

후처리

  1. waitthe mixture was left
  2. waitto stand for three hours

출처 및 근거

ORD 기록
ord-86d93c301391450cb70c8a9187b58abc
출처 데이터셋
uspto-grants-1991_09
특허 번호
US05047174

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