Homoallyl bromide → (4-Bromobutyl)(ethoxy)dimethylsilane

HRID 730249

반응식

HRID 730249 반응식
[CH3:1][SiH:2]([CH3:6])[O:3][CH2:4][CH3:5].[Br:7][CH2:8][CH2:9][CH:10]=[CH2:11]>[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Ru].[Ru].[Ru]>[Br:7][CH2:8][CH2:9][CH2:10][CH2:11][Si:2]([CH3:6])([CH3:1])[O:3][CH2:4][CH3:5]

참가 물질

4

반응물 2

HCID 21241Homoallyl bromide2회HCID 61772Ethoxydimethylsilane2회

생성물 1

HCID 22928485(4-Bromobutyl)(ethoxy)dimethylsilane

시약·촉매·용매 1

HCID 6096991Triruthenium dodecacarbonyl촉매

반응 조건

온도
80 °C

실험 절차

800 g of 4-bromo-1-butene were reacted with 15% excess of dimethylethoxysilane (939 ml). In a 2 l reactor 0.5 g of Ru3(CO)12 and 800 ml of 4-bromo-1-butene were brought under nitrogen and 939 ml of dimethylethoxysilane were added under nitrogen and the mixture was brought at 65° C. After 0.5 h the bath temperature was raised to 80° C. and the mixture was allowed to react overnight. After distillation 1329 g (93.7%) of 4-bromobutyl-dimethyl-ethoxysilane were isolated.

후처리

  1. customwas brought at 65° C
  2. customto react overnight
  3. distillationAfter distillation 1329 g (93.7%) of 4-bromobutyl-dimethyl-ethoxysilane
  4. customwere isolated

출처 및 근거

ORD 기록
ord-2f52ef34652041d382f5ed23b13db685
출처 데이터셋
uspto-grants-2009_09
특허 번호
US07582703B2

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