루테늄 카보닐

Triruthenium dodecacarbonyl

HCID 6096991

노트 반응

부분 구조 검색 유사 구조 찾기

기본 정보

CAS: 15243-33-1
표준 SMILES: [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Ru].[Ru].[Ru]
InChIKey: NQZFAUXPNWSLBI-UHFFFAOYSA-N
분자식: C12O12Ru3
평균 분자량: 639.3 g/mol

이름 및 식별자

우선 이름: Triruthenium dodecacarbonyl
IUPAC: carbon monoxide;ruthenium
현지명: 루테늄 카보닐
영어명: Ruthenium carbonyl
분자식: C12O12Ru3
분자량: 639.33

이름 및 동의어

Triruthenium dodecacarbonylRefChem:900088DTXCID901473651DTXSID901015348Ruthenium, dodecacarbonyltri, triangulo239-287-415243-33-1EINECS 239-287-4Ruthenium, dodecacarbonyltri-, trianguloRu3(CO)12MFCD00011209Ruthenium dodecacarbonyl

이름 더 보기

루테늄카르보닐루테늄카보닐루테늄카보닐(RUTHENIUMCARBONYL)DODECACARBONYLTRIRUTHENIUMpentaoxoniumRUTHENIUM CARBONYLRutheniumcarbonyl,99%Ruthenium carbonyl 99%carbon monoxide rutheniumDIRUTHENIUM DODECACARBONYLRuthenium,dodecacarbonyltri-

C12O12Ru3Ru3 (CO)12QAA24333AKOS015916383SY009926T2181dodecakis(methanidylidyneoxidanium) trirutheniumRuthenium carbonyl,; tri-Ruthenium dodecacarbonyl

데이터베이스 식별자

CAS: 15243-33-1
PubChem CID: 6096991
EC Number: 239-287-4

물성

구조 계산 물성

극성 표면적: 12 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 12
회전 가능 결합 수: 0
무거운 원자 수: 27
형식 전하: 0
복잡도: 10

실험 및 물리화학적 성질

Chemical ClassesMetals -> Metals, Organic Compounds

Physical DescriptionOrange crystals; [MSDSonline]

물리화학적 성질

녹는점: 150 °C · 150 °C
저장 조건: Inert atmosphere,Room Temperature
용해도: 탄화수소(예: 헥산, 시클로헥산, 벤젠) 및 아세톤에 약간 용해됩니다.
물리적 상태: 수정 같은
색상: 오렌지 레드
InChI: InChI=1S/12CO.3Ru/c12*1-2;;;
InChIKey: NQZFAUXPNWSLBI-UHFFFAOYSA-N
SMILES: [O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[Ru].[Ru].[Ru]
EPA: Ruthenium, dodecacarbonyltri-, triangulo (15243-33-1)

화학적 성질

The substance appears as orange plates or powder and is soluble in non-polar organic solvents.

안전 및 규제

GHS 분류

GHS Classification · 4건

Warning

H302 (34.3%): Harmful if swallowed [Warning Acute toxicity, oral]

P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P317, P319, P321, P330, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 67 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Hazards SummaryToxic by ingestion or inhalation; [MSDSonline]

Hazard Classes and CategoriesAcute Tox. 4 (34.3%)

안전 데이터

wgk: 3
tsca: TSCA listed
ridadr: 1325
HS 번호: 28439000
risk_code: 11-20-2017/11/20
hazard_code: F,Xn
safety_code: 24/25
포장분류: II
위험 등급: 6.1
기존화학 물질: KE-34786
위험 참고 사항: Flammable/Harmful
Hazard Classifications: Acute Tox. 4 Inhalation
스토리지 클래스: 11 - Combustible Solids

화학 및 산업

용도 및 제조

General Manufacturing InformationRuthenium, dodecacarbonyltri-, triangulo: ACTIVE

응용 분야 · 3건

개요Triruthenium dodecacarbonyl is a metal carbonyl complex, classified as an inorganic compound. Its molecular formula is Ru3(CO)12, with a molecular weight of 639.33. It possesses D3h symmetry and a core composed of a Ru equilateral triangle. Each Ru atom is attached to two axial and two equatorial CO ligands. Unlike triiron dodecacarbonyl, this compound does not contain any bridge bonds. It is commonly employed as a precursor for various organoruthenium compounds.

용도Ruthenium carbonyl is a H-transfer catalyst. It is used in carbonylation catalysis of the allylic amination of unactivated olefins by nitroarenes, reductive carbonylation of mononitro aromatic compounds to carbamates, and as a catalyst for cycloaddition reactions. It is employed as a precursor for the synthesis of Ru nanoparticles. Catalyst used in the intermolecular [3+2+1] cycloaddition of alpha,beta-unsaturated ketones with silylacetylenes and carbon monoxide, to produce alpha-pyrones. Catalyzes the coupling of silanes with thiols, alcohols and amines with high turnover number (TON) and high turnover frequency (TOF).

일반 설명Atomic number of base material: 44 Ruthenium