Toluene → Benzene, ethenyl-, polymer with 1,3-butadiene

HRID 734954노트

반응식

HRID 734954 반응식
[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.C([Al](CC(C)C)CC(C)C)C(C)C.[C:22]1(C)[CH:27]=CC=[CH:24][CH:23]=1.Cl(O)(=O)=O.C(O)C>C=CC=C>[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[CH2:27]=[CH:22][CH:23]=[CH2:24]

참가 물질

6

반응물 4

HCID 1140TolueneHCID 7501StyreneHCID 16682931TriisobutylaluminumHCID 21282719Chloric acid ethanol

생성물 1

HCID 62697Benzene, ethenyl-, polymer with 1,3-butadiene

시약·촉매·용매 1

HCID 78451,3-Butadiene용매

실험 절차

To a polymerization reactor under high purity nitrogen atmosphere, 50 ml of purified styrene and 50 ml of 1,3-butadiene were introduced and reaction temperature was controlled to 25° C. Then, 5 ml of triisobutylaluminum (1,0 M toluene solution) and 5 ml of methylaluminoxane (2.1 M toluene solution, Akzo Company product) were sequentially introduced. 5 ml (50 μmol of Ti) of toluene solution in which the metallocene catalyst is dissolved was added while vigorously agitating. After agitating for 2 hours, 10 wt % of chloric acid-ethanol solution was added to terminate a reaction the reactant was filtered, washed with ethanol and dried in a vacuum oven of 50° C. to obtain a final styrene/1,3-butadiene copolymer. Polymerization results and physical properties of polymers for each catalyst are shown in Table 5.

후처리

  1. customreaction temperature
  2. customwas controlled to 25° C
  3. additionwas added
  4. stirringAfter agitating for 2 hours
  5. customto terminate
  6. customa reaction the reactant
  7. filtrationwas filtered
  8. washwashed with ethanol
  9. customdried in a vacuum oven of 50° C.

출처 및 근거

ORD 기록
ord-2eeb79b02aa347b1aed9261405322901
출처 데이터셋
uspto-grants-2009_09
특허 번호
US07592401B2

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