홈MCP워크벤치Skills
홈워크벤치알림마이페이지
llms.txt · MCP 가이드개인정보처리방침 · 이용약관 · 지원v1.8.0
  1. 홈
  2. /반응

Triethylamine → Tert-butyl-(3-chlorobiphenyl-4-ylethynyl)dimethylsilane

HRID 735061
노트
인쇄 미리보기

반응식

HRID 735061 반응식
[Si:1]([C:8]#[CH:9])([C:4]([CH3:7])([CH3:6])[CH3:5])([CH3:3])[CH3:2].FC(F)(F)S(O[C:16]1[CH:21]=[CH:20][C:19]([C:22]2[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=2)=[CH:18][C:17]=1[Cl:28])(=O)=O.C(N(CC)CC)C>CN(C=O)C.C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.Cl[Pd]Cl.[Cu]I>[C:4]([Si:1]([C:8]#[C:9][C:16]1[CH:21]=[CH:20][C:19]([C:22]2[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=2)=[CH:18][C:17]=1[Cl:28])([CH3:3])[CH3:2])([CH3:7])([CH3:6])[CH3:5]
참가 물질실험 절차출처 및 근거반응 노트

참가 물질

7

반응물 3

HCID 8471TriethylamineHCID 2757281(tert-Butyldimethylsilyl)acetyleneHCID 180010793-Chlorobiphenyl-4-yl trifluoromethanesulfonate

생성물 1

HCID 68816298Tert-butyl-(3-chlorobiphenyl-4-ylethynyl)dimethylsilane

시약·촉매·용매 3

HCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)촉매
HCID 6102075
Dichlorobis(triphenylphosphine)palladium
촉매
HCID 6228Dimethylformamide용매

실험 절차

0.84 g (1.2 mmol) of bis-(triphenylphosphine)palladium (II) chloride, 0.23 g (1.2 mmol) of copper (I) iodide, and 6.28 mL (33.6 mmol) of (tert-butyldimethylsilyl)acetylene is added under an argon atmosphere to a solution of 8.1 g (24 mmol) of 3-chlorobiphenyl-4-yl trifluoromethanesulfonate in 50 mL of absolute DMF and 13.31 mL (96 mmol) of triethylamine.

출처 및 근거

ORD 기록
ord-ef609e1871c64a76a13ef6d6e918cd23
출처 데이터셋
uspto-grants-2009_09
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US07592373B2

반응 노트

불러오는 중…

이 페이지에서참가 물질실험 절차출처 및 근거반응 노트