Toluene → 4,6,8a-Trimethyl-3,4,4a,5,8,8a-hexahydronaphthalen-1(2H)-one

HRID 735399노트

반응식

HRID 735399 반응식
[CH3:1][C:2]1[C:3](=[O:9])[CH2:4][CH2:5][CH:6]([CH3:8])[CH:7]=1.[Cl-].[Cl-].[Cl-].[Al+3].C=[CH:15][C:16](=[CH2:18])[CH3:17].[C:19]1(C)C=CC=CC=1>>[CH3:8][CH:6]1[CH:7]2[C:2]([CH3:19])([CH2:1][CH:15]=[C:16]([CH3:18])[CH2:17]2)[C:3](=[O:9])[CH2:4][CH2:5]1

참가 물질

5

반응물 4

HCID 1140TolueneHCID 6557IsopreneHCID 6451240Aluminum(III) ChlorideHCID 131494292,4-Dimethylcyclohex-2-en-1-one

생성물 1

HCID 137165354,6,8a-Trimethyl-3,4,4a,5,8,8a-hexahydronaphthalen-1(2H)-one

실험 절차

2,4-Dimethyl-2-cyclohexen-1-one (40 g, 0.32 mmol), Aluminium trichloride (10.7 g, 0.08 mmol), Isoprene (326 g, 4.8 mol), Toluene (500 ml)

출처 및 근거

ORD 기록
ord-74a1fd38203b4a7681065a596b1ad7c9
출처 데이터셋
uspto-grants-2009_09
특허 번호
US07592492B2

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