Butanal → 2-Propyl-1,3-dioxane

HRID 73813노트

반응식

HRID 73813 반응식
[CH:1](=[O:5])[CH2:2][CH2:3][CH3:4].[CH2:6](O)[CH2:7][CH2:8][OH:9].P(=O)(O)(O)O.C(=O)CCC.O>O>[CH2:2]([CH:1]1[O:9][CH2:8][CH2:7][CH2:6][O:5]1)[CH2:3][CH3:4]

참가 물질

6

반응물 4

HCID 261ButanalHCID 1004Phosphoric AcidHCID 104421,3-PropanediolHCID 86675365Butyraldehyde water

생성물 1

HCID 2839812-Propyl-1,3-dioxane

시약·촉매·용매 1

HCID 962Water용매

실험 절차

Examples 5-7 are carried out using the apparatus described above. Prior to each example, the column is heated to 100° C. with boiling water as described above. Butyraldehyde is fed through the bottom feed plate and a mixture of 1,3-propanediol and 500 ppmw phosphoric acid is fed through the upper feed plate at rates described in Table I. A butyraldehyde/water azeotrope is condensed overhead at 73° C. The basepot reaches a maximum temperature of 165° C. Material is removed from the basepot throughout the run. The material separates into two phases, each of which is analyzed by gas chromatography. The results are listed in Table II.

후처리

  1. customcondensed overhead at 73° C
  2. customa maximum temperature of 165° C
  3. customMaterial is removed from the basepot throughout the run

출처 및 근거

ORD 기록
ord-f8a3daac2477484bad7123e64e1056c4
출처 데이터셋
uspto-grants-2014_09
특허 번호
US08829207B2

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