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Styrene → Prop-2-enenitrile--ethenylbenzene (1/1)

HRID 747394
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HRID 747394 반응식
[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[C:9](#[N:12])[CH:10]=[CH2:11].C(OS(C1C=CC=CC=1)(=O)=O)CCCCCCCCCCC.P([O-])([O-])([O-])=O.[Ca+2].P([O-])([O-])([O-])=O.[Ca+2].[Ca+2]>O>[CH2:11]=[CH:10][C:9]#[N:12].[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1
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참가 물질

6

반응물 4

HCID 7501StyreneHCID 7855AcrylonitrileHCID 15900Dodecyl benzenesulfonateHCID 24456Tricalcium Phosphate

생성물 1

HCID 62696Prop-2-enenitrile--ethenylbenzene (1/1)

시약·촉매·용매 1

HCID 962Water용매

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온도
85 °C

실험 절차

A copolymer resin composed of styrene and acrylonitrile was prepared by suspension polymerization as follows. Two hundred parts by weight of water, 0.02 part by weight of dodecylbenzenesulfonate, and 1 part by weight of calcium phosphate were charged in an 8-L polymerization apparatus. After removal of oxygen by proper nitrogen substitution with stirring, the mixture was heated to 85° C. In the mixture was added 75 parts by weight of styrene, 25 parts by weight of acrylonitrile, and 0.8 part by weight of benzoyl peroxide at the same time, and the resulting mixture was stirred for five hours. To the resulting mixture was further added 0.8 part by weight of benzoyl peroxide, and the resulting mixture was stirred for five hours to terminate the reaction. A styrene-acrylonitrile copolymer resin was obtained by dehydration. The refraction index was 1.57.

후처리

  1. customwas prepared by suspension polymerization
  2. customAfter removal of oxygen by proper nitrogen substitution
  3. additionIn the mixture was added 75 parts by weight of styrene, 25 parts by weight of acrylonitrile, and 0.8 part by weight of benzoyl peroxide at the same time
  4. stirringthe resulting mixture was stirred for five hours
  5. additionTo the resulting mixture was further added 0.8 part by weight of benzoyl peroxide
  6. stirringthe resulting mixture was stirred for five hours
  7. customto terminate
  8. customthe reaction

출처 및 근거

ORD 기록
ord-9e8a1ecdb7c448088d379fd20accd19d
출처 데이터셋
uspto-grants-2008_07
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US07396876B2

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