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llms.txt · MCP 가이드개인정보처리방침 · 이용약관 · 지원v1.8.0
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Hydrochloric Acid → Ethylimidazolium phenol salt

HRID 76209
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HRID 76209 반응식
[C:1]1([Si](OC)(OC)OC)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C([O:16][Si](O[CH2:25][CH3:26])(OCC)OCC)C.C[Si](OCC)(OCC)OCC.C(OCO[Si](CCC1C=CC=CC=1)(OC)OC)(C)(C)C.Cl.C(OCC(O)C)C.C([C:68]1[NH:69][CH:70]=[CH:71][N:72]=1)C>O.C(O)C.CC(C)=O>[C:1]1([OH:16])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH2:70]([N+:69]1[CH:26]=[CH:25][NH:72][CH:68]=1)[CH3:71]
참가 물질실험 절차후처리출처 및 근거반응 노트

참가 물질

11

반응물 7

HCID 313Hydrochloric Acid2회HCID 6517TetraethoxysilaneHCID 152871-Ethoxy-2-propanolHCID 16241TriethoxymethylsilaneHCID 18137TrimethoxyphenylsilaneHCID 661302-EthylimidazoleHCID 67001992Tert-butoxyphenylethyltrimethoxysilane

생성물

1
HCID 131731792Ethylimidazolium phenol salt

시약·촉매·용매 3

HCID 180Acetone용매HCID 702Ethanol용매HCID 962Water용매

실험 절차

4.99 g of phenyltrimethoxysilane, 67.99 g of tetraethoxysilane, 26.90 g of methyltriethoxysilane, 0.17 g of tert-butoxyphenylethyltrimethoxysilane, and 150 g of acetone were charged into a 500 mL flask to be dissolved and the resultant mixed solution was warmed while stirring the mixed solution with a magnetic stirrer to reflux. Next, 33.07 g of a 0.01 M hydrochloric acid aqueous solution was added to the mixed solution. The reaction was carried out for 240 minutes and then the resultant reaction solution was cooled down to room temperature. Then, 200 g of propylene glycol monoethyl ether was added to the reaction solution, and ethanol, water and hydrochloric acid being reaction by-products were distilled off under reduced pressure to obtain a hydrolysis-condensation product. To the hydrolysis-condensation product, 0.05 g of ethylimidazole was added to obtain an ethylimidazolium phenol salt-containing Si polymer. The obtained polymer corresponded to a polymer having four types of unit structures of Formula (3-18). The molecular weight Mw of the obtained polymer measured by GPC was found to be 1,500 in terms of polystyrene.

후처리

  1. dissolutionto be dissolved
  2. additionthe resultant mixed solution
  3. temperaturewas warmed
  4. temperatureto reflux
  5. customthe resultant reaction solution
  6. distillationwere distilled off under reduced pressure
  7. customto obtain a hydrolysis-condensation product

출처 및 근거

ORD 기록
ord-39ee17805ebf4d2798c4eb3fd69ec3c2
출처 데이터셋
uspto-grants-2014_09
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US08835093B2

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