Dichloromethane → 1-(t-Butoxycarbonyl)-4-(t-butyldimethylsilyloxy)piperidin-3-one

반응식

[C:1]([O:2][CH2:3][CH:4]=[C:7]1[CH2:8][N:9]([C:21](=[O:22])[O:23][C:24]([CH3:25])([CH3:26])[CH3:27])[CH2:10][CH2:11][CH:12]1[O:13][Si:14]([CH3:15])([CH3:16])[C:17]([CH3:18])([CH3:19])[CH3:20])(=[O:5])[CH3:6].[Cl:31][CH2:32][Cl:33].[O-:28][O+:29]=[O:30]>>[C:7]1(=[O:28])[CH2:8][N:9]([C:21](=[O:22])[O:23][C:24]([CH3:25])([CH3:26])[CH3:27])[CH2:10][CH2:11][CH:12]1[O:13][Si:14]([CH3:15])([CH3:16])[C:17]([CH3:18])([CH3:19])[CH3:20]

참가 물질

반응물 3

HCID 6344Dichloromethane

HCID 24823Ozone

HCID 68767251Tert-butyl 3-(2-acetyloxyethylidene)-4-[tert-butyl(dimethyl)silyl]oxypiperidine-1-carboxylate

생성물 1

HCID 231387171-(t-Butoxycarbonyl)-4-(t-butyldimethylsilyloxy)piperidin-3-one

출처 및 근거

ORD 기록: ord-81b3eca98b534bac8e2b8adc799787d9
출처 데이터셋: Test data from https://doi.org/10.1039/C8SC04228D
DOI: 10.1039/C8SC04228D

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