Ethyl formate → Cyclooctanone, 2-(hydroxymethylene)-

HRID 839738노트

반응식

HRID 839738 반응식
[C:1]1(=[O:9])[CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[CH:10](OCC)=[O:11]>>[OH:11][CH:10]=[C:2]1[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][C:1]1=[O:9]

참가 물질

3

반응물 2

HCID 8025Ethyl formateHCID 10403Cyclooctanone

생성물 1

HCID 1382068Cyclooctanone, 2-(hydroxymethylene)-

실험 절차

As in previous examples, 126 g of cyclooctanone, XXVIc, was reacted with ethyl formate to give 95 g (0.62 mol) of 2-hydroxymethylene-cyclooctanone, XXVIIc, bp 87°-92° C (0.4 mm).

출처 및 근거

ORD 기록
ord-164b083debe14b1ba8a9c4d89d87367f
출처 데이터셋
uspto-grants-1978_06
특허 번호
US04096336

반응 노트

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