1-Dodecanethiol → Ethyl Acrylate

HRID 847415

반응식

HRID 847415 반응식
[CH2:1](S)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].CCCC[CH2:18][C:19]([C:23]([O:25]OC(C)(C)C)=[O:24])([CH2:21]C)[CH3:20]>C1(C)C=CC=CC=1>[C:23]([O:25][CH2:1][CH3:2])(=[O:24])[CH:19]=[CH2:21].[C:23]([O:25][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12])(=[O:24])[C:19]([CH3:20])=[CH2:18]

참가 물질

5

반응물 2

HCID 81951-DodecanethiolHCID 71359725Tert-butyl 2-ethyl-2-methylheptaneperoxoate

생성물 2

HCID 8821Ethyl AcrylateHCID 18510Decyl methacrylate

시약·촉매·용매 1

HCID 1140Toluene용매

실험 절차

350 g of toluene, 135 g of ethyl acrylate, and 15 g of n-decyl methacrylate were polymerized with stirring in a reaction flask at 50°-60° C. under argon with 0.3 g of dodecyl mercaptan as a regulator and 2 g of t-butyl perneodecanoate as initiator. After about 30 minutes of reaction, the mixture was precipitated in methanol and the polymer was dried under vacuum.

후처리

  1. customAfter about 30 minutes of reaction
  2. customthe mixture was precipitated in methanol
  3. customthe polymer was dried under vacuum

출처 및 근거

ORD 기록
ord-c2b49c75adc9482d84cd3eef32fdd950
출처 데이터셋
uspto-grants-1992_08
특허 번호
US05141993

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