Lithium Hexamethyldisilazide → Chromium tris(bis(trimethylsilyl)amide)

HRID 849263노트

반응식

HRID 849263 반응식
[Cl-].[Cl-].[Cl-].[Cr+3:4].[CH3:5][Si:6]([N-:9][Si:10]([CH3:13])([CH3:12])[CH3:11])([CH3:8])[CH3:7].[Li+]>>[CH3:5][Si:6]([N-:9][Si:10]([CH3:13])([CH3:12])[CH3:11])([CH3:8])[CH3:7].[CH3:5][Si:6]([N-:9][Si:10]([CH3:13])([CH3:12])[CH3:11])([CH3:8])[CH3:7].[CH3:5][Si:6]([N-:9][Si:10]([CH3:13])([CH3:12])[CH3:11])([CH3:8])[CH3:7].[Cr+3:4]

참가 물질

3

반응물 2

HCID 2733832Lithium HexamethyldisilazideHCID 6452300Chromium(3+) trichloride

생성물 1

HCID 6097019Chromium tris(bis(trimethylsilyl)amide)

실험 절차

In accordance with the method disclosed in J. Chem. Soc. (A), 1433 (1971), chromium (III) tris(bistrimethylsilylamide) was synthesized by reaction of anhydrous chromium trichloride anhalide with lithiumbistrimethylsilylamide.

출처 및 근거

ORD 기록
ord-d49c44fa511d42d099ae63133ff923c7
출처 데이터셋
uspto-grants-2000_01
특허 번호
US06011127

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