Dimethyl Sulfoxide → Benzene, 1,3-bis(1-phenylethenyl)-

HRID 864100

반응식

HRID 864100 반응식
[CH2:1]=[CH:2][C:3](=[CH2:5])C.[Li][CH:7]([CH2:9][CH3:10])[CH3:8].CN(C)[CH2:13][CH2:14]N(C)CCN(C)C.[C:23]([C:26]1[CH:31]=[CH:30][CH:29]=[C:28]([C:32]([CH3:34])=[CH2:33])[CH:27]=1)([CH3:25])=C.[CH3:35]S(C)=O>O1CCCC1>[C:8]1([C:23]([C:26]2[CH:31]=[CH:30][CH:29]=[C:28]([C:32]([C:34]3[CH:1]=[CH:2][CH:3]=[CH:5][CH:35]=3)=[CH2:33])[CH:27]=2)=[CH2:25])[CH:14]=[CH:13][CH:10]=[CH:9][CH:7]=1

참가 물질

7

반응물 5

HCID 679Dimethyl SulfoxideHCID 6557IsopreneHCID 18196PentamethyldiethylenetriamineHCID 773531,3-DiisopropenylbenzeneHCID 178418400CID 53628100

생성물 1

HCID 118622Benzene, 1,3-bis(1-phenylethenyl)-

시약·촉매·용매 1

HCID 8028Tetrahydrofuran용매

실험 절차

Isoprene, sec-BuLi solution (1.3M in cyclohexane), anhydrous tetrahydrofuran (THF), anhydrous dimethylsulfoxide (DMSO), pentamethyldiethylenetriamine (PMDETA) and 1,3-diisopropenylbenzene (1) were obtained from Aldrich Chemical Company, Milwaukee, Wis. 1,3-bis(1-phenylethenyl)benzene (3) was obtained from the Dow Chemical Company, Midland, Mich.

출처 및 근거

ORD 기록
ord-592ca8bafb7d45659bb753cf662c6d1a
출처 데이터셋
uspto-grants-1996_10
특허 번호
US05561210

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