Iodine → 3-(Cyclohexyldisulfanyl)-2-methylfuran

HRID 866432

반응식

HRID 866432 반응식
[CH3:1][C:2]1[O:3][CH:4]=[CH:5][C:6]=1[SH:7].[CH:8]1([SH:14])[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9]1.C(=O)([O-])[O-].[Na+].[Na+].II>C(OCC)C.O>[CH:8]1([S:14][S:7][C:6]2[CH:5]=[CH:4][O:3][C:2]=2[CH3:1])[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9]1

참가 물질

7

반응물 4

HCID 807Iodine2회HCID 10340Sodium CarbonateHCID 15290CyclohexanethiolHCID 342862-Methyl-3-furanthiol

생성물 1

HCID 203138903-(Cyclohexyldisulfanyl)-2-methylfuran

시약·촉매·용매 2

HCID 962Water용매HCID 3283Diethyl Ether용매2회

실험 절차

0.57 Grams (0.0050 moles) of 2-methyl-3-furanthiol and 1.16 grams (0.01 moles) of cyclohexylmercaptan are dissolved in 12 ml of diethyl ether. 0.8 Grams (0.0075 moles) of sodium carbonate dissolved in 8 ml water is added to the reaction mass. Over a period of 10 minutes, a solution of 1.9 grams (0.0075 moles) of iodine dissolved in 6 ml diethyl ether is added to the reaction mass with stirring until the iodine color remains. The reaction mass is then stirred over a period of 45 minutes.

후처리

  1. additionis added to the reaction mass
  2. additionis added to the reaction mass

출처 및 근거

ORD 기록
ord-5bf50225e8f643f8bec01a20944659ad
출처 데이터셋
uspto-grants-1978_07
특허 번호
US04098910

연결된 노트

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