tert-Butyl hydroperoxide → HCID 20318133, 화합물

반응식

[C:1](N=NC(Cl)(C)C)(C)(C)[CH3:2].[K].C(OO)(C)(C)C.[C:18]([N:22]=[N:23][C:24]([O:27][O:28][C:29]([CH3:32])(C)C)([CH3:26])[CH3:25])([CH3:21])([CH3:20])[CH3:19].C(N=NC(O)(C)C)(C)(C)C>>[C:18]([N:22]=[N:23][C:24]([O:27][O:28][CH2:29][CH2:32][CH2:1][CH3:2])([CH3:25])[CH3:26])([CH3:19])([CH3:20])[CH3:21]

참가 물질

반응물 5

HCID 6410tert-Butyl hydroperoxide

HCID 945822-Propanol, 2-((1,1-dimethylethyl)azo)-

HCID 5462222Potassium

HCID 156443492-t-Butylazo-2-chloropropane

HCID 20393238HCID 20393238, 화합물

생성물 1

HCID 20318133HCID 20318133, 화합물

실험 절차

Crude 2-t-butylazo-2-butylperoxypropane was prepared by reacting 2-t-butylazo-2-chloropropane with an aqueous solution of the potassium salt of t-butyl hydroperoxide according to the method described in MacLeay, Lange and Sheppard application Ser. No. 426,411 filed Dec. 19, 1973, (which is incorporated herein by reference). The resultant product contained approximately 75% 2-t-butylazo -2-t-butylperoxypropane and 25% 2-t-butylazo-2-hydroxy-propane (which has been marketed as "LUCEL 3").