Allyl phenyl ether → HCID 14328878, 화합물

HRID 867959

반응식

HRID 867959 반응식
[N:1]1([CH2:6][C:7]([C:11]2[CH:20]=[CH:19][C:18]3[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=3)[CH:12]=2)=[N+:8]([O-:10])[CH3:9])[CH:5]=[CH:4][N:3]=[CH:2]1.[CH2:21]([O:24][C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1)[CH:22]=[CH2:23]>C1(C)C=CC=CC=1>[N:1]1([CH2:6][C:7]2([C:11]3[CH:20]=[CH:19][C:18]4[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=4)[CH:12]=3)[CH2:23][CH:22]([CH2:21][O:24][C:25]3[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=3)[O:10][N:8]2[CH3:9])[CH:5]=[CH:4][N:3]=[CH:2]1

참가 물질

4

반응물 2

HCID 74458Allyl phenyl etherHCID 867424722-(1H-Imidazol-1-yl)-N-methyl-1-(2-naphthalenyl)ethanimine N-oxide

생성물 1

HCID 14328878HCID 14328878, 화합물

시약·촉매·용매 1

HCID 1140Toluene용매

실험 절차

A mixture of compound 2 (9.0 g, 0.034 mol) and phenyl allyl ether (6.98 ml, 0.051 mol) in 200 ml of toluene is refluxed for 48 hours, cooled and evaporated under vacuum. The semisolid that remained (7.30 g, 54%) is crystallized from ether and recrystallized from ethyl acetate to give tan crystals. Yield: 2.4 g (18%); m.p. 176°-178° C. (Found: C, 74.96; H, 6.41; N, 10.40. C25H25N3O2 requires: C, 75.16; H, 6.31; N, 10.52).

후처리

  1. temperatureis refluxed for 48 hours
  2. temperaturecooled
  3. customevaporated under vacuum
  4. customis crystallized from ether
  5. customrecrystallized from ethyl acetate
  6. customto give tan crystals

출처 및 근거

ORD 기록
ord-40739d68791d434b838e2b7febef88e8
출처 데이터셋
uspto-grants-1988_10
특허 번호
US04777263

연결된 노트

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