Oxalyl chloride → Acetyl chloride, (benzoyloxy)-

HRID 868190노트

반응식

HRID 868190 반응식
[C:1]([O:9][CH2:10][C:11]([OH:13])=O)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C(Cl)(=O)C([Cl:17])=O>C(Cl)(Cl)Cl>[C:1]([O:9][CH2:10][C:11]([Cl:17])=[O:13])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

참가 물질

4

반응물 2

HCID 65578Oxalyl chloride2회HCID 12647149HCID 12647149, 화합물

생성물 1

HCID 10888895Acetyl chloride, (benzoyloxy)-

시약·촉매·용매 1

HCID 6212Chloroform용매

실험 절차

4.1 g (0.023 m) Benzoyloxy acetic acid (as synthesized in Example XIII) was combined with 2.96 ml (4.3 g, 0.032 m) oxalyl chloride in 50 ml petroleum ether. This was stirred under a CaSO4 drying tube for 5 hrs., at which time 2.0 ml more oxalyl chloride and 50 ml chloroform were added. The reaction was stirred overnight.

후처리

  1. stirringThe reaction was stirred overnight

출처 및 근거

ORD 기록
ord-9f193701636d40df9f6068968c6d3028
출처 데이터셋
uspto-grants-1988_10
특허 번호
US04778618

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