Triethylamine → Benzyl 4-chlorobenzoyloxycarbamate

HRID 879023

반응식

HRID 879023 반응식
[Cl:1][C:2]1[CH:10]=[CH:9][C:5]([C:6](Cl)=[O:7])=[CH:4][CH:3]=1.[OH:11][NH:12][C:13](=[O:22])[O:14][CH2:15][C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1.C(N(CC)CC)C>C(OCC)C>[Cl:1][C:2]1[CH:10]=[CH:9][C:5]([C:6]([O:11][NH:12][C:13](=[O:22])[O:14][CH2:15][C:16]2[CH:17]=[CH:18][CH:19]=[CH:20][CH:21]=2)=[O:7])=[CH:4][CH:3]=1

참가 물질

5

반응물 3

HCID 8471TriethylamineHCID 85014-Chlorobenzoyl chlorideHCID 18907Benzyl hydroxycarbamate

생성물 1

HCID 51033117Benzyl 4-chlorobenzoyloxycarbamate

시약·촉매·용매 1

HCID 3283Diethyl Ether용매

실험 절차

4-Chlorobenzoyl chloride (13.1 mL, 102 mmol) is added slowly to a solution of benzyl hydroxycarbamate (19.0 g, 114 mmol) and triethylamine (14.4 mL, 104 mmol) in diethyl ether (500 mL) at 0° C. then stirred at room temperature for 1 h. The reaction is

출처 및 근거

ORD 기록
ord-61ae2cfa3efb4b06b28f8c9207977e98
출처 데이터셋
uspto-grants-2015_03
특허 번호
US08987504B2

연결된 노트

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