1-Octene → Gamma-Decalactone

HRID 894940

반응식

HRID 894940 반응식
[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH:7]=[CH2:8].[C:9]([O-:12])(=[O:11])[CH3:10].[K+]>C(O)(=O)C>[CH2:6]([CH:7]1[O:12][C:9](=[O:11])[CH2:10][CH2:8]1)[CH2:5][CH2:4][CH2:3][CH2:2][CH3:1]

참가 물질

4

반응물 2

HCID 81251-OcteneHCID 517044Potassium Acetate

생성물 1

HCID 12813Gamma-Decalactone수율 31%

시약·촉매·용매 1

HCID 176Acetic Acid용매

실험 절차

Octene-1 in an amount of 2.2 grams and 23.6 grams of ceric acetate were refluxed under nitrogen in 200 milliliters of glacial acetic acid containing 60 grams of potassium acetate for less than 0.4 hour, there being obtained a 31% yield of gamma-n-hexyl butyrolactone.

출처 및 근거

ORD 기록
ord-569dc1de6fc747dcb74dbc631e0b4bcf
출처 데이터셋
uspto-grants-1981_08
특허 번호
US04285868

연결된 노트

불러오는 중…