Benzaldehyde → Methanaminium, N-methyl-N-(phenylmethylene)-, chloride

HRID 8980

반응식

[CH3:1][NH:2][CH3:3].[CH:4](=O)[C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1.C([Cl:15])(=O)C>>[Cl-:15].[CH:4](=[N+:2]([CH3:3])[CH3:1])[C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1

참가 물질

반응물 3

HCID 240Benzaldehyde

HCID 674Dimethylamine

HCID 6367Acetyl chloride

생성물 1

HCID 11073839Methanaminium, N-methyl-N-(phenylmethylene)-, chloride

실험 절차

The reaction of 32.0 ml (0.213 mol) dimethylamine solution and 8.0 ml (0.079 mol) benzaldehyde in accordance with general synthesis instructions 1 and subsequent reaction with 4.7 ml (0.079 mol) acetyl chloride in accordance with general synthesis instructions 3 gave 9.5 g (corresponding to 70.7% of the yield calculated by theory) of benzylidene-dimethyl-ammonium chloride.

후처리

customwith general synthesis instructions 3

출처 및 근거

ORD 기록: ord-a8a93c2e2b784f2fbed88552562dcb80
출처 데이터셋: uspto-grants-2006_08
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US07091220B2

연결된 노트

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