Peracetic Acid → Acetic Acid Hexane

HRID 903108

반응식

HRID 903108 반응식
[C:1]([O-:4])(=[O:3])[CH3:2].[Tl+].[CH3:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].C(OO)(=O)C.C(C1C=CC(C(C)C(OC)=O)=CC=1)C(C)C>C(O)(=O)C.CCOCC>[C:1]([OH:4])(=[O:3])[CH3:2].[CH3:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11]

참가 물질

7

반응물 4

HCID 6585Peracetic AcidHCID 8058Hexane2회HCID 11247thallium(I) acetateHCID 109101Ibuprofen methyl ester

생성물 1

HCID 22590778Acetic Acid Hexane

시약·촉매·용매 2

HCID 176Acetic Acid용매2회HCID 3283Diethyl Ether용매

실험 절차

To a solution of 260 mg. (1.0 mmole) of thallium (I) acetate and 24 mg. (0.1 mmole) of hydrated manganese diacetate in 3 ml. of 80 percent aqueous acetic acid and 4.5 ml. of hexane, there was added 0.3 ml. (about 2.0 mmole) of 42 percent peracetic acid solution in acetic acid. After five minutes of stirring there was added 100 mg. (0.5 mmole) of 4-isobutylpropiophenone methyl enol ether in 0.5 ml. of hexane. After stirring the mixture for about thirty-five minutes, a glc analysis of a sample of the reaction mixture indicated that about 89 percent of the enol ether had been converted to methyl 2-(4-isobutylphenyl)propionate, based on the starting wnol ether.

후처리

  1. additionwas added 100 mg
  2. stirringAfter stirring the mixture for about thirty-five minutes

출처 및 근거

ORD 기록
ord-d426f638516b408a919da14614283435
출처 데이터셋
uspto-grants-1980_10
특허 번호
US04226790

연결된 노트

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