Acetone → HCID 70525545, 화합물

HRID 905092

반응식

HRID 905092 반응식
[C:1]([C:6]1[CH:11]=[C:10]([C:12]([CH2:15][CH3:16])([CH3:14])[CH3:13])[CH:9]=[CH:8][C:7]=1O)([CH2:4][CH3:5])([CH3:3])[CH3:2].[CH2:18](Br)[CH:19]=[CH2:20].[C:22](=[O:25])([O-])[O-].[CH3:26][C:27]([CH3:29])=O>>[C:1]([C:6]1[CH:11]=[C:10]([C:12]([CH2:15][CH3:16])([CH3:14])[CH3:13])[CH:9]=[CH:8][C:7]=1[CH:20]=[CH:19][CH2:18][O:25][CH2:22][CH:26]=[CH:27][C:29]1[CH:8]=[CH:7][C:6]([C:1]([CH2:4][CH3:5])([CH3:3])[CH3:2])=[CH:11][C:10]=1[C:12]([CH2:15][CH3:16])([CH3:14])[CH3:13])([CH2:4][CH3:5])([CH3:3])[CH3:2]

참가 물질

5

반응물 4

HCID 180AcetoneHCID 7841Allyl bromideHCID 84552,4-Di-tert-pentylphenolHCID 19660Carbonate Ion

생성물 1

HCID 70525545HCID 70525545, 화합물

실험 절차

117.2 g of 2,4-di-t-amylphenol and 90.7 g of allylbromide was dissolved in 500 ml of acetone. Thereto was added 103.5 g of pottassium carbonate and refluxed in a water bath for 20 hours. Then reaction mixture was filtered under suction and filtration residue was rinsed with 100 ml of acetone, thereafter this was again mixed with the mother solution and then under reduced pressure acetone and excess allyl bromide was distilled out.

후처리

  1. temperaturerefluxed in a water bath for 20 hours
  2. customThen reaction mixture
  3. filtrationwas filtered under suction and filtration residue
  4. washwas rinsed with 100 ml of acetone
  5. additionthis was again mixed with the mother solution
  6. distillationunder reduced pressure acetone and excess allyl bromide was distilled out

출처 및 근거

ORD 기록
ord-6ce65696a38043df969eb3d936abe02e
출처 데이터셋
uspto-grants-1983_12
특허 번호
US04421846

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