Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Water → (E)-3,3-dimethyl-N-(trimethylsilylmethyl)butan-1-imine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Water | HCID 962 | — |
| 반응물 | 3,3-Dimethylbutanal | HCID 76335 | — |
| 반응물 | 1-(Trimethylsilyl)methylamine | HCID 87488 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | (E)-3,3-dimethyl-N-(trimethylsilylmethyl)butan-1-imine | HCID 58222849 | 97.1% |
반응 단계
To a solution of (aminomethyl)trimethylsilane (Fluka) (1.03 g, 10 mmol) in dichloromethane (20 mL) was added 3,3-dimethyl-butyraldehyde (Aldrich) (1.0 g, 10 mmol). The reaction mixture was stirred at room temperature for 3 h. Water was added. The organic layer was separated, washed with brine, dried over MgSO4, and concentrated to give [3,3-dimethyl-but-(E)-ylidene]-trimethylsilanylmethyl-amine as a colorless oil (1.8 g, 97%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08017607B2 |
| 출처 데이터셋 | uspto-grants-2011_09 |
| ORD ID | ord-4a11f2a0381e45a9a17185ffee7a25dc |
| 출처 메모 | uspto-grants-2011_09 |