Vinyl Acetate → Triethylene glycol monovinyl ether monoacetate

HRID 916918

반응식

HRID 916918 반응식
[C:1]([O-:4])(=[O:3])[CH3:2].[Na+].C(O)COCCOCCO.C(OC=C)(=O)C.[CH:22]([O:24][CH2:25][CH2:26][O:27][CH2:28][CH2:29][O:30][CH2:31][CH2:32]OC=C)=[CH2:23].C(OCCOCCOCCO)=C>C1(C)C=CC=CC=1>[C:1]([O:4][CH2:32][CH2:31][O:30][CH2:29][CH2:28][O:27][CH2:26][CH2:25][O:24][CH:22]=[CH2:23])(=[O:3])[CH3:2]

참가 물질

7

반응물 5

HCID 7904Vinyl AcetateHCID 8172Triethylene GlycolHCID 517045Sodium AcetateHCID 575880Ethanol, 2-(2-(2-(ethenyloxy)ethoxy)ethoxy)-HCID 3033992Triethylene glycol divinyl ether

생성물 1

HCID 22034547Triethylene glycol monovinyl ether monoacetate

시약·촉매·용매 1

HCID 1140Toluene용매

반응 조건

온도
100 °C

실험 절차

To a mixture of di-μ-chlorobis(1,5-cyclooctadiene)diiridium(I) [Ir(cod)Cl]2 (0.01 mmol) and sodium acetate (1.2 mmol) in toluene (2.0 ml),triethylene glycol (1 mmol) and vinyl acetate (4 mmol) were added, followed by stirring at 100° C. in an atmosphere of argon gas for 6 hours. The reaction mixture was analyzed by gas chromatography to find that triethylene glycol divinyl ether, triethylene glycol monovinyl ether, and triethylene glycol monovinyl ether monoacetate were produced in yields of 63%, 3%, and 18%, respectively, with a conversion from triethylene glycol of 100%.

후처리

  1. additionwere added

출처 및 근거

ORD 기록
ord-1d5810fe818a4bc79002725ea7c7a0d3
출처 데이터셋
uspto-grants-2007_09
특허 번호
US07271297B2

연결된 노트

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