Carbon Disulfide → (2-{[(5-Methyl-1H-imidazol-4-yl)methyl]sulfanyl}ethyl)carbamodithioic acid

HRID 918018

반응식

HRID 918018 반응식
[CH3:1][C:2]1[N:3]=[CH:4][NH:5][C:6]=1[CH2:7][S:8][CH2:9][CH2:10][NH2:11].[C:12](=[S:14])=[S:13]>C(O)C>[CH3:1][C:2]1[NH:3][CH:4]=[N:5][C:6]=1[CH2:7][S:8][CH2:9][CH2:10][NH:11][C:12](=[S:13])[SH:14]

참가 물질

4

반응물 2

HCID 6348Carbon DisulfideHCID 178433288HCID 178433288, 화합물

생성물 1

HCID 15566013(2-{[(5-Methyl-1H-imidazol-4-yl)methyl]sulfanyl}ethyl)carbamodithioic acid

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

A solution of 4-methyl-5-((2-aminoethyl)thiomethyl) imidazole (10.2 g) in ethanol (75 ml) was added slowly, with stirring, to carbon disulphide (200 ml). The mixture was set aside overnight at room temperature and the solid formed was collected and recrystallized from aqueous isopropyl alcohol to afford N-[2-((5-methyl-4-imidazolyl)-methylthio)ethyl]dithiocarbamic acid (9.8 g)., m.p. 127°-129°.

후처리

  1. customthe solid formed
  2. customwas collected
  3. customrecrystallized from aqueous isopropyl alcohol

출처 및 근거

ORD 기록
ord-abb376b9e5524fe7b2df40e537864ab0
출처 데이터셋
uspto-grants-1976_07
특허 번호
US03968227

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