2,6-Dipropylphenol → 2,6-Dipropyl4-propionylphenol

HRID 9250노트

반응식

HRID 9250 반응식
[C:1]([O-:5])(=O)[CH2:2][CH3:3].[Na+].[CH2:7]([C:10]1[CH:15]=[CH:14][CH:13]=[C:12]([CH2:16][CH2:17][CH3:18])[C:11]=1[OH:19])[CH2:8][CH3:9]>OS(C(F)(F)F)(=O)=O>[CH2:16]([C:12]1[CH:13]=[C:14]([C:1](=[O:5])[CH2:2][CH3:3])[CH:15]=[C:10]([CH2:7][CH2:8][CH3:9])[C:11]=1[OH:19])[CH2:17][CH3:18]

참가 물질

4

반응물 2

HCID 811072,6-DipropylphenolHCID 2723816Sodium Propionate

생성물 1

HCID 113108722,6-Dipropyl4-propionylphenol

시약·촉매·용매 1

HCID 62406Trifluoromethanesulfonic acid용매

실험 절차

Sodium propanoate (0.88 g, 1.5 eq) and 2,6-dipropylphenol (1.09 g, 1.0 eq) were combined in Triflic Acid (5.0 g) as in Example 13, step 1. The resulting waxy solid was purified by chromatography on silica gel using ethyl acetate:hexanes:acetic acid (10:90:1) to give the titled phenol.

후처리

  1. customThe resulting waxy solid was purified by chromatography on silica gel

출처 및 근거

ORD 기록
ord-ec11d9e4f3f449f6a915145c8ea66bec
출처 데이터셋
uspto-grants-2006_08
특허 번호
US07091230B2

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