Bis(eta-cyclopentadienyl) iron → HCID 178460910, 화합물

HRID 962952

반응식

HRID 962952 반응식
[CH-:1]1[CH:5]=[CH:4][CH:3]=[CH:2]1.[CH-:6]1[CH:10]=[CH:9][CH:8]=[CH:7]1.[Fe+2:11].[CH2:12]([Si:15]([CH3:18])([CH3:17])[Cl:16])[CH:13]=[CH2:14]>>[Cl:16][Si:15]([CH3:18])([CH3:17])[CH2:12][CH:13]([C-:1]1[CH:5]=[CH:4][CH:3]=[CH:2]1)[CH3:14].[CH-:6]1[CH:10]=[CH:9][CH:8]=[CH:7]1.[Fe+2:11]

참가 물질

3

반응물 2

HCID 7611Bis(eta-cyclopentadienyl) ironHCID 77646Allylchlorodimethylsilane

생성물 1

HCID 178460910HCID 178460910, 화합물수율 20%

실험 절차

In the same apparatus and procedures as EXAMPLE 1 above, 0.30 g(1.61 mmol) of ferrocene was reacted with 0.92 mL(6.3 mmol) of allyldimethylchlorosilane under dry nitrogen atmospheric pressure for 2 hrs. After the addition of the catalyst solution, the reaction mixture was stirred for an additional 2 hrs to complete the alkylation. The solvent was distilled off at atmospheric pressure and the products were then extracted with 20.0 ml. of hexane. The reaction products were distilled under vacuum at 200° C. and at 0.5 torr, and produced 0.1 g of (3-chloro-1,3-dimethyl-3-silabutyl)ferrocene (yield; 20%). The remaining products were vacuum distilled at 300° C. and at 0.5 torr, and 0.55 g of bis(3-chloro-1,3-dimethyl-3-silabutyl)ferrocenes(yield; 38%) was obtained.

후처리

  1. additionAfter the addition of the catalyst solution
  2. distillationThe solvent was distilled off at atmospheric pressure
  3. extractionthe products were then extracted with 20.0 ml
  4. distillationThe reaction products were distilled under vacuum at 200° C. and at 0.5 torr

출처 및 근거

ORD 기록
ord-a86a59e552dd4c28b3bf30e9d9778bf0
출처 데이터셋
uspto-grants-1998_06
특허 번호
US05760263

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