디시클로펜타디에닐 철

Bis(eta-cyclopentadienyl) iron

HCID 7611CAS 102-54-5

기본 정보

표준 SMILES
[Fe+2].c1cc[cH-]c1.c1cc[cH-]c1
InChIKey
KTWOOEGAPBSYNW-UHFFFAOYSA-N
분자식
C10H10Fe
평균 분자량
186.03 g/mol
단동위원소 질량
186.013186

이름 및 식별자

우선 이름
Bis(eta-cyclopentadienyl) iron
IUPAC
bis(cyclopenta-1,3-diene);iron(2+)
현지명
디시클로펜타디에닐 철
영어명
Ferrocene
분자식
C10H10Fe
분자량
186.03

이름 및 동의어

CCRIS 3195HSDB 2878EINECS 203-039-3UNII-U96PKG90JQAI3-23119FERROCENE [MI]FERROCENE [HSDB]EC 203-039-3SCHEMBL29681ferrous;cyclopenta-1,3-dieneBis(eta-cyclopentadienyl) ironFe(C5H5)2
이름 더 보기
디시클로펜타디에닐철디시클로펜타디에닐철페로센ermaotieFERROCENBIS(CYCLOPENTADIENYL)IRONBIS(CYCLOPENTADIEN)IRONcataneFerrotsenOxolan-3-olDICYCLOPENTADIENYLIRONIRON DICYCLOPENTADIENYLFERROCENE
DTXCID105326Bis( cyclopentadienyl)eisen(II)Tox21_202514NCGC00091936-01NCGC00260063-01CAS-102-54-5Q/TY.J08.19-2022NS00041498

데이터베이스 식별자

CAS
102-54-5
PubChem CID
7611
UNII
U96PKG90JQ

물성

구조 계산 물성

극성 표면적
0 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
2
회전 가능 결합 수
0
무거운 원자 수
11

물리화학적 성질

녹는점
172 · 172-174 °C (lit.)
끓는 점
249 °C · 249 °C (lit.)
밀도
1.49 · 1.490
증기압
0.03 mm · 0.03 mm Hg ( 40 °C)
인화점
100 °C · 100°C
저장 조건
30 °C · Store below +30°C.
화학적 성질 · 1건

Ferrocene, a metallocene, appears as bright orange salt-like crystals when crystallized from alcohol. It has a camphor-like odor and forms an orange crystalline solid. The compound is insoluble in water but soluble in benzene, ether, and alcohol, with an iron content of 29.4–30.6%.

안전 및 규제

안전 데이터

OEB
B
OEL
TWA: 10 mg/m3 (total)
wgk
2
tsca
TSCA listed
rtecs
LK0700000
ridadr
UN 1325 4.1/PG 2

화학 및 산업

응용 분야 · 2건

용도Ferrocene is used as a catalyst for vulcanization, acceleration, and polymerization, as a chemical intermediate for polymeric compounds such as high temperature polymers, as an antiknock additive for gasoline, as a coating for missiles and satellites, and as a high-temperature lubricant.

일반 설명Ferrocene appears as orange crystalline solid or orange-yellow powder. Sublimes above 212 °F. Camphor odor. (NTP, 1992)

제조 방법

생산 방법Ferrocene is produced from the reaction of cyclopentadiene with reduced iron in the presence of metal oxides. There is also a two-stage production process in which produced iron (II)oxide (stage 1) is reacted with cyclopentadiene.

공급사50 곳

国药集团化学试剂有限公司86-21-63210123 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
科瑞迪化学400-821-5857 021-64326257 · [email protected]
上海将来实业股份有限公司400-0066400 13621662912 · [email protected]
추가 설명 · 1건

정의ferrocene: An orange-red crystallinesolid, Fe(C5H5)2; m.p. 173°C. Itcan be made by adding the ioniccompound Na+C5H5- (cyclopentadienylsodium, made from sodium andcyclopentadiene) to iron(III) chloride.In ferrocene, the two rings are parallel,with the iron ion sandwiched betweenthem (hence the namesandwich compound: see formula).The bonding is between pi orbitalson the rings and d-orbitals on theFe2+ ion. The compound can undergoelectrophilic substitution on theC5H5rings (they have some aromatic character).It can also be oxidized to theblue ion (C5H5)2Fe+. Ferrocene is the first of a class of similar complexescalled sandwich compounds. Its systematicname is di-π-cyclopentadienyliron(II).

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104건

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