Bis(eta-cyclopentadienyl) iron → HCID 178447720, 화합물

HRID 962955노트

반응식

HRID 962955 반응식
[CH-:1]1[CH:5]=[CH:4][CH:3]=[CH:2]1.[CH-:6]1[CH:10]=[CH:9][CH:8]=[CH:7]1.[Fe+2:11].[CH2:12]([Si:15]([CH2:18][CH2:19][CH2:20][CH2:21][CH2:22]C)([Cl:17])[Cl:16])[CH:13]=[CH2:14]>>[Cl:16][Si:15]([Cl:17])([CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[CH2:12][CH:13]([C-:1]1[CH:5]=[CH:4][CH:3]=[CH:2]1)[CH3:14].[CH-:6]1[CH:10]=[CH:9][CH:8]=[CH:7]1.[Fe+2:11]

참가 물질

3

반응물 2

HCID 7611Bis(eta-cyclopentadienyl) ironHCID 11218382Allylhexyldichlorosilane

생성물 1

HCID 178447720HCID 178447720, 화합물수율 26%

실험 절차

In the same apparatus and procedures as EXAMPLE 1, 0.60 g(3.22 mmol) of ferrocene was reacted with 1.45 g(6.44 mmol) of allyl -n-hexyldichlorosilane under the dry nitrogen atmospheric pressure for 2 hrs. After the addition of the catalyst solution, the reaction mixture was stirred for 2 hrs to complete the alkylation. The solvent was distilled off at atmospheric pressure and the products were then extracted with 20.0 mL of hexane. By vacuum distillation of the reaction products at 300° C. and at 0.5 torr, (3,3-dichloro-1-methyl-3-silaoctyl)ferrocene [yield: 26%(based on the reacted ferrocene), bp:(165-170° C./0.5 torr)] was obtained.

후처리

  1. additionAfter the addition of the catalyst solution
  2. distillationThe solvent was distilled off at atmospheric pressure
  3. extractionthe products were then extracted with 20.0 mL of hexane
  4. distillationBy vacuum distillation of the reaction products at 300° C.
  5. custom(165-170° C./0.5 torr)] was obtained

출처 및 근거

ORD 기록
ord-49b3d7d981324ce4b1e8d367f1ebc403
출처 데이터셋
uspto-grants-1998_06
특허 번호
US05760263

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