Palladium Chloride → Palladium triflate

HRID 964709노트

반응식

HRID 964709 반응식
Cl[Pd:2]Cl.[OH:4][S:5]([C:8]([F:11])([F:10])[F:9])(=[O:7])=[O:6]>C(Cl)Cl>[O-:7][S:5]([C:8]([F:11])([F:10])[F:9])(=[O:6])=[O:4].[Pd+2:2].[O-:7][S:5]([C:8]([F:11])([F:10])[F:9])(=[O:6])=[O:4]

참가 물질

4

반응물 2

HCID 24290Palladium ChlorideHCID 62406Trifluoromethanesulfonic acid

생성물 1

HCID 11603820Palladium triflate

시약·촉매·용매 1

HCID 6344Dichloromethane용매

실험 절차

PdCl2 (1.0 g, 5.6 mmol) was slurried in CH2Cl2 (20 mL) and triflic acid (1.7 g, 11.3 mmol) was added dropwise. The mixture was stirred at room temperature overnight. The solvent was removed and 0.9 g of rust color solid was collected. 19F NMR (CDCl3): δ-78.5.

후처리

  1. customThe solvent was removed
  2. custom0.9 g of rust color solid was collected

출처 및 근거

ORD 기록
ord-0c79103282e745e19f28a3bfb8cac528
출처 데이터셋
uspto-grants-1998_06
특허 번호
US05770678

반응 노트

불러오는 중…