2-Mesityl-3-nitropyridine → 2-Mesityl-3-pyridinamine

HRID 966014

반응식

HRID 966014 반응식
[C:1]1([CH3:18])[CH:6]=[C:5]([CH3:7])[CH:4]=[C:3]([CH3:8])[C:2]=1[C:9]1[C:14]([N+:15]([O-])=O)=[CH:13][CH:12]=[CH:11][N:10]=1>C(O)C.[H][H].[C].[Pd]>[C:1]1([CH3:18])[CH:6]=[C:5]([CH3:7])[CH:4]=[C:3]([CH3:8])[C:2]=1[C:9]1[C:14]([NH2:15])=[CH:13][CH:12]=[CH:11][N:10]=1

참가 물질

5

반응물 1

HCID 222494912-Mesityl-3-nitropyridine

생성물 1

HCID 167414262-Mesityl-3-pyridinamine수율 106.5%

시약·촉매·용매 3

HCID 178418390HCID 178418390, 화합물촉매HCID 702Ethanol용매HCID 178418361HCID 178418361, 화합물용매

실험 절차

Palladium-carbon (10%, 0.6 g) was added to a solution of 2-mesityl-3-nitropyridine (5.99 g, 23 mmol) in ethanol (120 mL), followed by stirring for one day in hydrogen atmospher. The mixture was filtered through Celite and evaporated, to give the title compound (5.2 g) as white crystals.

후처리

  1. filtrationThe mixture was filtered through Celite
  2. customevaporated

출처 및 근거

ORD 기록
ord-c73ee1167547434ca4212285a5e42e77
출처 데이터셋
uspto-grants-2005_10
특허 번호
US06951865B2

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