2,4,6-Tri-tert-butylphenol → HCID 178506938, 화합물

HRID 966140

반응식

HRID 966140 반응식
[C:1]([C:5]1[CH:10]=[C:9]([C:11]([CH3:14])([CH3:13])[CH3:12])[CH:8]=[C:7]([C:15]([CH3:18])([CH3:17])[CH3:16])[C:6]=1[OH:19])([CH3:4])([CH3:3])[CH3:2].C([Li:24])CCC>C1(C)C=CC=CC=1>[C:1]([C:5]1[CH:10]=[C:9]([C:11]([CH3:14])([CH3:13])[CH3:12])[CH:8]=[C:7]([C:15]([CH3:18])([CH3:17])[CH3:16])[C:6]=1[O:19][Li:24])([CH3:4])([CH3:3])[CH3:2]

참가 물질

4

반응물 2

HCID 129022,4,6-Tri-tert-butylphenolHCID 178418339Butyllithium

생성물 1

HCID 178506938HCID 178506938, 화합물수율 96%

시약·촉매·용매 1

HCID 1140Toluene용매

실험 절차

Both 10 mmol (2.2 g) of monocyclopentadienyl titanium chloride(CpTiCl3) and 100 ml of toluene were added to a 200 ml Schlenk reactor in the atmosphere of inert gas. Then, 10 mmol of 2,4,6-tri-t-butyl phenoxy lithium, so obtained from the reaction between 2,4,6-tri-t-butyl phenol and n-butyl lithium, was slowly added to the mixture. The reactional solution was stirred at room temperature and stood for 1 hour. After 1 hour, some mixture was collected and was analyzed by 1H-NMR spectroscopy to ascertain the reaction results.

출처 및 근거

ORD 기록
ord-87be3b2b23a44669b7700c30a49ba912
출처 데이터셋
uspto-grants-2005_10
특허 번호
US06951906B1

연결된 노트

불러오는 중…