Propargyl alcohol → HCID 22314150, 화합물

반응식

[CH3:1][C:2]1[S:6][C:5]2[CH:7]=[C:8](OS(C(F)(F)F)(=O)=O)[CH:9]=[CH:10][C:4]=2[C:3]=1[C:19]1[CH:24]=[CH:23][C:22]([C:25]([F:28])([F:27])[F:26])=[CH:21][CH:20]=1.[CH2:29]([OH:32])[C:30]#[CH:31]>>[CH3:1][C:2]1[S:6][C:5]2[CH:7]=[C:8]([C:31]#[C:30][CH2:29][OH:32])[CH:9]=[CH:10][C:4]=2[C:3]=1[C:19]1[CH:24]=[CH:23][C:22]([C:25]([F:26])([F:27])[F:28])=[CH:21][CH:20]=1

참가 물질

반응물 2

HCID 7859Propargyl alcohol

HCID 86585425HCID 86585425, 화합물

생성물 1

HCID 22314150HCID 22314150, 화합물

실험 절차

In analogy to example 13.1, the Trifluoro-methanesulfonic acid 2-methyl-3-(4-trifluoromethyl-phenyl)-benzo[b]thiophen-6-yl ester was reacted with 2-propyn-1-ol to yield the 3-[2-Methyl-3-(4-trifluoromethyl-phenyl)-benzo[b]thiophen-6-yl]-prop-2-yn-1-ol as yellow oil, MS: 346 (M+).

출처 및 근거

ORD 기록: ord-6f7169a8a7224ad19198366ffd893aa6
출처 데이터셋: uspto-grants-2005_10
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06951879B2

반응 노트

불러오는 중…