Propylene Glycol → HCID 20347326, 화합물

HRID 972911노트

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HRID 972911 반응식
[N+:1]([C:4]1[CH:5]=[C:6]([CH:9]=[C:10]([N+:19]([O-:21])=[O:20])[C:11]=1[N:12]([CH2:16][CH2:17][CH3:18])[CH2:13][CH2:14][CH3:15])[CH:7]=[O:8])([O-:3])=[O:2].[CH2:22]([OH:26])[CH:23](O)[CH3:24].C1(C)C=CC(S(O)(=O)=O)=CC=1>C1C=CC=CC=1>[CH3:24][CH:23]1[CH2:22][O:26][CH:7]([C:6]2[CH:5]=[C:4]([N+:1]([O-:3])=[O:2])[C:11]([N:12]([CH2:13][CH2:14][CH3:15])[CH2:16][CH2:17][CH3:18])=[C:10]([N+:19]([O-:21])=[O:20])[CH:9]=2)[O:8]1

참가 물질

5

반응물 3

HCID 1030Propylene GlycolHCID 6101p-Toluenesulfonic acidHCID 203473334-(Dipropylamino)-3,5-dinitrobenzaldehyde

생성물 1

HCID 20347326HCID 20347326, 화합물

시약·촉매·용매 1

HCID 241Benzene용매

실험 절차

A mixture of 3.0 g. of 3,5-dinitro-4-(dipropylamino)benzaldehyde, 2.0 ml. of 1,2-propanediol, 75 ml. of benzene, and a small amount of p-toluenesulfonic acid was refluxed for about 4 hours, using a Dean-Stark trap to collect the evolved water. The reaction product mixture was cooled and extracted successively with saturated aqueous sodium bicarbonate solution, and brine, and then dried. The drying agent was filtered off and the benzene solution passed through an aluminum oxide column. The eluate was collected and evaporated. A total of 2.2 g. of 4-(4-methyl-1,3-dioxolan-2-yl)-2,6-dinitro-N,N-dipropylaniline was isolated as an oil.

후처리

  1. additionA mixture of 3.0 g
  2. customto collect the evolved water
  3. temperatureThe reaction product mixture was cooled
  4. extractionextracted successively with saturated aqueous sodium bicarbonate solution, and brine
  5. customdried
  6. filtrationThe drying agent was filtered off
  7. customThe eluate was collected
  8. customevaporated

출처 및 근거

ORD 기록
ord-756e1266b1a34bc6aeee0d99d06f0525
출처 데이터셋
uspto-grants-1977_10
특허 번호
US04054439

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