Oxygen → Adamantanone

HRID 9743

반응식

HRID 9743 반응식
[CH:1]12[CH2:10][CH:5]3[CH2:6][CH:7]([CH2:9][CH:3]([CH2:4]3)[CH2:2]1)[CH2:8]2.[OH:11]N1C(=O)N(O)C(=O)N(O)[C:13]1=[O:22].[O:23]=O>C(O)(=O)C>[CH:1]12[CH2:10][CH:5]3[CH2:6][CH:7]([CH2:9][CH:3]([CH2:4]3)[C:2]1=[O:11])[CH2:8]2.[C:13]12([OH:22])[CH2:9][CH:3]3[CH2:4][CH:5]([CH2:10][CH:1]([CH2:2]3)[CH2:8]1)[CH2:6]2.[C:13]12([OH:22])[CH2:9][CH:7]3[CH2:6][CH:5]([CH2:10][C:1]([OH:23])([CH2:8]3)[CH2:2]1)[CH2:4]2

참가 물질

7

반응물 3

HCID 977OxygenHCID 9238AdamantaneHCID 104197231,3,5-Trihydroxy-1,3,5-triazinane-2,4,6-trione

생성물 3

HCID 64151AdamantanoneHCID 641521-AdamantanolHCID 5738291,3-Adamantanediol

시약·촉매·용매 1

HCID 176Acetic Acid용매

실험 절차

A mixture of 1.00 g of adamantane, 0.026 g of hexahydro-1,3,5-trihydroxy-1,3,5-triazine-2,4,6-trione (2% by mole relative to adamantane), 9.0 g of acetic acid and 0.003 g of acetylacetonatovanadium(III) was stirred at 85° C. in an atmosphere of oxygene gas (1 atm=0.1 MPa) for 6 hours. The resulting product in the reaction mixture was analyzed by gas chromatography and was found to yield 2-adamantanon, 1-adamantanol and 1,3-adamantanediol in 3%, 27% and 4% yields, respectively, at 41% conversion of adamantane.

출처 및 근거

ORD 기록
ord-32b442668f9d4fb18085508f5ff084c7
출처 데이터셋
uspto-grants-2006_08
특허 번호
US07091342B2

연결된 노트

불러오는 중…