Hydrogen Peroxide → 6-Hydroxy-2-naphthoic acid
반응식
O(C([C:6]1[CH:7]=[C:8]2[C:13](=[CH:14][CH:15]=1)[CH:12]=[C:11]([C:16]([OH:18])=[O:17])[CH:10]=[CH:9]2)(C)C)O.[OH:19]C(C1C=C2C(=CC=1)C=C(C(O)=O)C=C2)(C)C.OO.Cl(O)(=O)(=O)=O>C(#N)C>[OH:19][C:6]1[CH:7]=[C:8]2[C:13](=[CH:14][CH:15]=1)[CH:12]=[C:11]([C:16]([OH:18])=[O:17])[CH:10]=[CH:9]2참가 물질
6
실험 절차
The above-mentioned white powdery material consisting of 6-(2-hydroperoxy-2-propyl)naphthalene-2-carboxylic acid and 6-(2-hydroxy-2-propyl)naphthalene-2-carboxylic acid was reacted in a solvent, acetonitrile, at 50° C. for 30 minutes adding hydrogen peroxide and perchloric acid. Thus, the two compounds were simultaneously subjected to acid decomposition to form 6-hydroxynaphthalene-2-carboxylic acid nearly quantitatively.
출처 및 근거
- ORD 기록
- ord-7bebab55606c4372881526927f25af06
- 출처 데이터셋
- uspto-grants-1987_01
- 특허 번호
- US04638087
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