Water → HCID 19824186, 화합물

HRID 981375

반응식

HRID 981375 반응식
[OH2:1].[C:2]([C:6]1[CH:11]=[C:10]([N:12]=O)[CH:9]=[C:8]([C:14]([CH3:17])([CH3:16])[CH3:15])[C:7]=1[OH:18])([CH3:5])([CH3:4])[CH3:3].ClCCl.[H][H].[CH3:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29]>[Pd]>[OH:18][C:7]1[C:6]([C:2]([CH3:5])([CH3:4])[CH3:3])=[CH:11][C:10]([NH:12][C:24](=[O:1])[CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:3][CH2:2][CH2:6][CH2:7][CH2:8][CH3:9])=[CH:9][C:8]=1[C:14]([CH3:17])([CH3:16])[CH3:15]

참가 물질

7

반응물 5

HCID 962WaterHCID 6344DichloromethaneHCID 8058HexaneHCID 70383Phenol, 2,6-bis(1,1-dimethylethyl)-4-nitroso-HCID 178418361HCID 178418361, 화합물2회

생성물 1

HCID 19824186HCID 19824186, 화합물

시약·촉매·용매 1

HCID 23938Palladium촉매

실험 절차

A 2 liter Parr bomb was charged with 210.5 g of 44.6% water wet (0.5 mole, pure, dry) 2,6-di-tert-butyl-4-nitrosophenol, 2.0 g of 5% Pd/C catalyst, 300 ml dichloromethane and 400 ml hexane. The nitrogen purged system was pressurized to 50 psi with hydrogen and the rate of hydrogen uptake noted. Hydrogenation was completed within one hour.

출처 및 근거

ORD 기록
ord-89e4a46da6b64ab080f7764d88a2ecde
출처 데이터셋
uspto-grants-1991_02
특허 번호
US04990671

연결된 노트

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