Benzene → HCID 67933141, 화합물

HRID 982459

반응식

HRID 982459 반응식
[CH2:1]([O:3][CH2:4][CH2:5][O:6][CH2:7][CH2:8][O:9][C:10]1[CH:15]=[CH:14][C:13]([CH2:16][CH:17]=[CH2:18])=[CH:12][CH:11]=1)[CH3:2].C1C=CC=CC=1.[CH3:25][SiH:26]([O:30][CH2:31][CH3:32])[O:27][CH2:28][CH3:29].C(O)C>[H+].[H+].Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl.C1COCC1>[CH3:25][Si:26]([O:30][CH2:31][CH3:32])([O:27][CH2:28][CH3:29])[CH2:18][CH2:17][CH2:16][C:13]1[CH:12]=[CH:11][C:10]([O:9][CH2:8][CH2:7][O:6][CH2:5][CH2:4][O:3][CH2:1][CH3:2])=[CH:15][CH:14]=1

참가 물질

7

반응물 4

HCID 241BenzeneHCID 702EthanolHCID 74848MethyldiethoxysilaneHCID 200680043-{4-[2-(2-Ethoxyethoxy)ethoxy]phenyl}-1-propene

생성물 1

HCID 67933141HCID 67933141, 화합물수율 97%

시약·촉매·용매 2

HCID 61859Chloroplatinic acid촉매HCID 8028Tetrahydrofuran용매

반응 조건

온도
85 °C

실험 절차

This compound was made by first heating a mixture of 2.8 g (0.011 mol) of 3-{4-[2-(2-ethoxyethoxy)ethoxy]phenyl}-1 -propene (prepared as in Example 1), 5 g of benzene and 1.1 equivalent of methyldiethoxysilane under an argon atmosphere at 85° C. for one hour. After one hour, a trace amount (0.01 μL) of 1 part chloroplatinic acid in 1 part ethanol and 98 parts THF was added and the mixture was heated overnight at 85° C. The product was isolated by distillation to give 4.2 g (97%) of methyl diethoxy 3-{4-[2-(2-ethoxyethoxy)ethoxy]phenyl}propysilane, bp 135° C./0.08mm; NMR (δ): 0.20(3H,s), 0.65(2H,m), 1.05(9H,t), 1.50(2H,m), 2.70(2H,t), 3.90(12H,m), 7.0(2H,d), 7.15(2H,d).

후처리

  1. temperatureby first heating
  2. customThe product was isolated by distillation

출처 및 근거

ORD 기록
ord-f800b64e428b4683a36637fade35041f
출처 데이터셋
uspto-grants-1991_02
특허 번호
US04996277

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