Isopropanol → Yttrium(iii) isopropoxide

HRID 982462

반응식

HRID 982462 반응식
[Y:1].[CH:2]([OH:5])([CH3:4])[CH3:3]>[Cl-].[Cl-].[Zn+2].[Zn]>[CH3:3][CH:2]([CH3:4])[O-:5].[Y+3:1].[CH3:3][CH:2]([CH3:4])[O-:5].[CH3:3][CH:2]([CH3:4])[O-:5]

참가 물질

5

반응물 2

HCID 3776IsopropanolHCID 23993Yttrium2회

생성물 1

HCID 11550724Yttrium(iii) isopropoxide수율 70%

시약·촉매·용매 2

HCID 23994Zinc촉매2회HCID 3007855Zincchloride촉매3회

실험 절차

The same procedure described in Example 3 was utilized except that ZnCl2 was substituted for zinc metal but was not milled with the yttrium. The milled yttrium, without zinc metal or zinc chloride, was reacted with a solution of isopropanol (500 cc) and 3 grams of ZnCl2 over a 24 hour period. Work-up of the reaction mixture yielded 41.6 grams (a 70% yield) of yttrium isopropoxide.

출처 및 근거

ORD 기록
ord-dac3355981c3471781afc681e54aba5f
출처 데이터셋
uspto-grants-1991_02
특허 번호
US04996300

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