Trifluoromethanesulfonic acid → 7,14-Dihydro-3,10-dimethylpentacene-5,12-dione

HRID 983750노트

반응식

HRID 983750 반응식
CC1C=CC(C[C:7]2[CH:15]=[C:14]([C:16](O)=[O:17])[C:13]([CH2:19][C:20]3[CH:25]=[CH:24][C:23]([CH3:26])=[CH:22][CH:21]=3)=[CH:12][C:8]=2[C:9]([OH:11])=O)=CC=1.FC(F)(F)S(O)(=O)=O>FC(F)(F)C(O)=O>[CH3:9][C:8]1[CH:7]=[CH:15][C:14]2[CH2:16][C:7]3[C:8]([C:9](=[O:11])[C:13]=2[CH:12]=1)=[CH:12][C:13]1[CH2:19][C:20]2[C:21](=[CH:22][C:23]([CH3:26])=[CH:24][CH:25]=2)[C:16](=[O:17])[C:14]=1[CH:15]=3

참가 물질

4

반응물 2

HCID 62406Trifluoromethanesulfonic acidHCID 117491572,5-Bis(4-methylbenzyl)terephthalic acid

생성물 1

HCID 114505987,14-Dihydro-3,10-dimethylpentacene-5,12-dione

시약·촉매·용매 1

HCID 6422Trifluoroacetic acid용매

실험 절차

To a mixture of 12.7 grams of 2,5-bis(4-methylbenzyl)terephthalic acid and 90 mL of trifluoroacetic acid was added 81.6 grams of trifluoromethanesulfonic acid. The mixture was stirred 22 hours at room temperature. The mixture was poured over 500 grams of ice. The resulting solid precipitate was collected by filtration, and washed with 750 mL of saturated aqueous sodium bicarbonate and then with 1 L of water until the filtrate was neutral to pH paper. The solid was washed with heptane and dried to give 7,14-dihydro-3,10-dimethylpentacene-5,12-dione.

후처리

  1. filtrationThe resulting solid precipitate was collected by filtration
  2. washwashed with 750 mL of saturated aqueous sodium bicarbonate
  3. washThe solid was washed with heptane
  4. customdried

출처 및 근거

ORD 기록
ord-8dc192f939934b578ad4c3dac4eee7a9
출처 데이터셋
uspto-grants-2005_03
특허 번호
US06864396B2

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